
Scheme 1: Synthesis of 4,4'-(5,5'-(1,4-phenylene)bis(1,3,4-oxadiazole-5,2-diyl) dianiline
Table 1: Characteristics of primary composites
DyeNo. |
DMF |
Methanol |
Ethanol |
λmax(nm) |
λmax(nm) |
λmax(nm) |
|
5a |
355, 490 |
345, 505 |
360, 520 |
5b |
360, 515 |
355, 507 |
345, 530 |
5c |
350, 525 |
345, 520 |
355, 520 |
5d |
335, 505 |
315, 505 |
320, 495 |
5e |
330, 510 |
330, 500 |
330, 505 |
Table 2: UV-Visible spectra of the synthesized dyes in different solvents
Dye No. |
K/S |
L* |
a* |
b* |
C* |
h° |
5a |
0.81 |
70.61 |
26.91 |
4.36 |
27.27 |
9.21 |
5b |
2.15 |
72.69 |
29.98 |
7.79 |
30.97 |
14.56 |
5c |
10.79 |
74.98 |
33.01 |
8.41 |
34.07 |
14.29 |
5d |
2.82 |
75.79 |
33.5 |
13.14 |
35.99 |
21.41 |
5e |
18.26 |
77.42 |
34.22 |
16.14 |
37.84 |
25.24 |
Table 3: Spectral data on cotton dyed samples
Dye No. |
K/S |
L* |
a* |
b* |
C* |
h° |
5a |
1.13 |
68.53 |
13.35 |
13.85 |
19.23 |
46.03 |
5b |
5.11 |
64.14 |
33.09 |
15.42 |
36.51 |
24.98 |
5c |
8.44 |
68.34 |
37.43 |
19.14 |
43.83 |
31.34 |
5d |
2.6 |
65.82 |
31.04 |
22.8 |
36.47 |
31.64 |
5e |
19.88 |
69.06 |
40.4 |
25.92 |
48.07 |
32.66 |
Table 4: Spectral data on wool dyed samples
Dye No |
Cotton dyed Fabric |
Wool dyed Fabric |
||||||
Wash fastness |
Light fastness |
Wash fastness |
Light fastness |
|||||
Staining (1-5) |
Colour Change |
Staining (1-5) |
Colour Change |
|||||
Cotton |
Wool |
Cotton |
Wool |
|||||
5a |
4-5 |
4-5 |
- |
4-5 |
4-5 |
4-5 |
- |
3-4 |
5b |
3 |
4-5 |
4 |
4 |
3-4 |
4-5 |
3-4 |
6 |
5c |
3 |
4-5 |
3-4 |
3-4 |
4 |
4-5 |
4-5 |
5 |
5d |
2 |
4-5 |
3 |
3-4 |
3 |
4-5 |
4 |
5 |
5e |
2 |
4 |
3 |
4 |
3 |
4-5 |
34 |
6-7 |
Table 5: Fastness evaluation of cotton and wool dyed fabric
Scheme 1: Synthesis of 4,4'-(5,5'-(1,4-phenylene)bis(1,3,4-oxadiazole-5,2-diyl) dianiline
Figure 1: The structures of synthesized dyes were verified with different spectroscopic techniques (Scheme 2).
Scheme 2: Synthesis of Novel Bis-azo Naphthol Based Disperse Dyes
Tables at a glance
Figures at a glance